Attraction between atoms or ions leads to a
chemical bond. According to the types of bonds contained in a molecule,
the physical properties including melting point, hardness, electrical
and thermal conductivity and solubility are determined. Chemical bonds
involve only the outermost or valence electrons of atoms. Using the
example of the simplest element, hydrogen, its two atoms on approaching
each other, cause electon-electron and proton-proton repulsions to
attempt separation of the atoms. But counterbalance by proton-electron
attraction fuses the two hydrogen atoms forming a bond.
This example demonstrates the gain, loss and
sharing of electrons by atoms for possession of the same number of
electrons as the noble gas in closest proximity on the periodic table.
With eight valence electrons (s2p6), all noble gases are chemically
stable in a phenomenon called the octet rule. But certain exceptions
are possible. Among them, one group of atoms has less than eight
electrons like hydrogen with only one. BeH2 has just four valence
electrons around Be, with Beryllium contributing two electrons and each
hydrogen with one. The second exception applies in elements in periods
4 and above. Their atoms can have over four surrounding valence pairs
in certain compounds.
Types of Chemical Bonds
Familiarity with three types of chemical bonds is required for the SAT
II Chemistry exam, ionic bonds, covalent bonds and metallic bonds.
Ionic Bonds
An electrostatic attraction between ions with opposite charges, cations
and anions causes ionic bonds. They usually involve metals and
nonmetals as elements active in ionic bonds are mostly from opposite
ends of the periodic table with an electronegativity difference
exceeding 1.67. Being very strong, ionic bonds in compounds increase
melting points and take a solid form in normal conditions. Finally, an
electron in an ionic bond is transferred from the less electronegative
atom to the more electronegative element. A prime example of an ionic
bond-content molecule is NaCl or table salt.
Covalent Bonds
Atoms may share electrons instead of transferring them from atom to
atom, resulting in covalent bonds. But the sharing is rarely ever equal
due to the difference in electronegativity value of each atom. The only
exception is the bond between two atoms of the same element. Covalent
bonds are said to be non-polar when the difference in electronegativity
of two atoms ranges from 0 to 0.4. Polar refers to electronegativity
difference between 0.4 and 1.67. For both non-polar and polar covalent
bonds, higher electronegativity in an element results in stronger
attraction of the electron pair. Carbon dioxide, CO2 molecules have two
bonds which are covalent bonds.
It is possible for covalent bonds to be single,
double or triple. A single bond occurs when only one pair of electrons
is shared. This single bond is a sigma bond with the electron density
being most pronounced along the line joining the two atoms.
Metallic Bonds
Metallic bonds are exclusive to metals alone, including aluminium,
gold, copper and iron. Each atom in a metal shares a bond with a number
of other metal atoms, thereby allowing their electrons unrestricted
movement within the metal structure. It is this specific phenomenon
that is behind the properties of metals being unique, an example being
their high conductivity.
That basically sums up the essence of chemical
bonds, the differences in various types and the reasons for molecular
structures being formed.
About the author:
Dr. George Grant is an experienced researcher in Bio-chemistry. He has
done extensive researches and experiments in the field. He is a
visiting faculty for some of the most reputed Science colleges. For
more information on Chemistry
Definitions and Chemical Equations.Please visit: http://www.chemicool.com
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